
MOFs在催化有机分子转化中的应用
Application of MOFs in Catalytic Conversion of Organic Molecules
金属有机框架化合物(MOF),又称多孔性配位聚合物,是有机配体与金属离子自组装而成的一类新型有机-无机杂化多孔材料,是纳米材料的重要组成部分。与其他多孔材料相比,MOFs具有较大的比表面积、高的孔隙率以及结构和性质可调等特性,使其在非均相催化领域具有良好的应用前景。本文首先对MOFs催化的背景进行简述,然后对近年来报道的MOFs用于有机分子催化转化反应的进展进行了综述及展望,以期为MOFs催化有机反应的设计和开发提供参考。
Metal-organic framework compounds (MOF), also known as porous coordination polymers, are a new type of organic-inorganic hybrid porous materials which are self-assembled from organic ligands and metal ions, and are an important part of nanomaterials. Compared to other porous materials, MOFs have a large surface area, high porosity and adjustable structure and properties, making them have a good application prospect in heterogeneous catalysis. In this paper, the background of MOFs catalysis is briefly reviewed, followed by a review and prospect of the recent progress of MOFs in catalytic conversion reactions of organic molecules, in order to provide a reference for the design and development of organic reactions catalyzed by MOFs.
1 Introduction
2 Knoevenagel Condensation catalyzed by MOFs
3 Suzuki-Miyaura Reaction catalyzed by MOFs
4 Mizoroki-Heck Reaction catalyzed by MOFs
5 Aldol Condensation catalyzed by MOFs
6 A3-Coupling Reaction catalyzed by MOFs
7 Cycloaddition of CO2catalyzed by MOFs
8 Oxidation and reduction of unsaturated hydrocarbons catalyzed by MOFs
9 Conclusion and outlook
金属有机框架材料 / 非均相催化 / 界面金属有机化学 / 有机分子 / 高附加值化学品
metal-organic framework / heterogeneous catalysis / interfacial organometallic chemistry / organic molecules / high value-added chemicals
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