光催化甲烷直接转化制甲醇提高甲烷转化率和甲醇选择性

韩春秋; 曹玥晗; 黄川; 吕伟峰; 周莹

doi:10.7536/PC231020

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化学进展 ›› 2024, Vol. 36 ›› Issue (6) : 867-877. DOI: 10.7536/PC231020

综述

光催化甲烷直接转化制甲醇提高甲烷转化率和甲醇选择性

韩春秋 ¹^,² ,
曹玥晗 ¹^,²^,^* ,
黄川 ² ,
吕伟峰 ² ,
周莹 ¹^,²^,^*

作者信息 +

Photocatalytic Methane Oxidation to Methanol in Promoting Methane Conversion Rate and Methanol Selectivity

Chunqiu Han ¹^,² ,
Yuehan Cao ¹^,²^,^* ,
Chuan Huang ² ,
Weifeng Lv ² ,
Ying Zhou ¹^,²^,^*

Author information +

文章历史 +

摘要

The photocatalytic direct conversion of methane (CH₄) to methanol (CH₃OH) provides an effective approach for chemical energy storage and the synthesis of high-value chemicals. However, because the activation of CH₄ molecules is difficult, and CH₃OH is more active than CH₄ and more prone to peroxidation, the conversion of CH₄ is low, and the selectivity of CH₃OH is also low. Therefore, the selective photocatalytic direct conversion of CH₄ to CH₃OH still faces great challenges. In this review, recent research ideas for improving CH₄ conversion and CH₃OH selectivity in photocatalytic CH₄ direct conversion to CH₃OH, as well as the corresponding catalyst design strategies, are summarized. In terms of improving the conversion rate of CH₄, it is mainly through improving the activation of active oxygen radicals or catalytic activation pathway to effectively activate CH₄. In terms of improving the selectivity of CH₃OH, it is mainly to inhibit the peroxidation of CH₃OH or to achieve the regeneration of CH₃OH. In order to improve the conversion of CH₄ and the selectivity of CH₃OH, the main strategies of catalytic design are loading cocatalyst, controlling the size of catalytic materials and constructing oxygen vacancies. Finally, the future research directions of photocatalytic direct conversion of CH₄ to CH₃OH are proposed in this review.

Abstract

Photocatalytic direct conversion of methane(CH₄)to methanol(CH₃OH)provides an effective way for efficient energy storage and the synthesis of high-value chemicals.However,due to the difficulty in activating CH₄molecules and the fact that CH₃OH is more reactive than CH₄and prone to peroxidation,the conversion rate of CH₄is low,and the selectivity of CH₃OH is low as well.Therefore,the selective photocatalytic direct conversion of CH₄to CH₃OH still faces significant challenges.This review focuses on the research ideas on promoting CH₄conversion rate and CH₃OH selectivity in recent years in the direct conversion of photocatalytic CH₄to CH₃OH,as well as the corresponding catalyst design strategies.In terms of promoting the CH₄conversion rate,the main research idea is to effectively activate CH₄by improving reactive oxygen radical activation or catalytic activation pathways.In terms of promoting CH₃OH selectivity,the main idea is to inhibit the peroxidation of CH₃OH or achieve CH₃OH regeneration.In order to improve the conversion rate of CH₄and the selectivity of CH₃OH,catalytic design strategies mainly include loading cocatalysts,controlling the size of catalytic materials and constructing oxygen vacancies.Finally,this review provides an outlook on the future research direction of photocatalytic direct conversion of CH₄to CH₃OH .

Contents

1 Introduction

2 Approach of promoting CH₄conversion rate

2.1 Reactive oxygen radical activation

2.2 Catalytic activation

3 Strategies for the design of catalysts to enhance the conversion rate of CH₄

3.1 Reactive radicals

3.2 Active site of photocatalysts

4 Approach of promoting CH₃OH selectivity

4.1 Inhibiting CH₃OH peroxidation

4.2 Achieving CH₃OH regeneration

5 Conclusion and outlook

导出引用

韩春秋 , 曹玥晗 , 黄川 , 等. 光催化甲烷直接转化制甲醇提高甲烷转化率和甲醇选择性[J]. 化学进展. 2024, 36(6): 867-877 https://doi.org/10.7536/PC231020

, , , et al. Photocatalytic Methane Oxidation to Methanol in Promoting Methane Conversion Rate and Methanol Selectivity[J]. Progress in Chemistry. 2024, 36(6): 867-877 https://doi.org/10.7536/PC231020

中图分类号： O643.3 O622.3

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