
Rare EarthDoped Lead Halide Perovskites: Synthesis, Properties and RadiationDetectors
Weiran Chen, Lin Ma, Ting Zhao, Zhengguang Yan, Jiawen Xiao, Zhenzhong Wang, Xiaodong Han
Prog Chem ›› 2023, Vol. 35 ›› Issue (12) : 1864-1880.
Rare EarthDoped Lead Halide Perovskites: Synthesis, Properties and RadiationDetectors
In recent years, lead halide perovskites have shown excellent performance in photovoltaic devices and photodetectors due to its excellent semiconductor properties and have become a hot spot in materials science.Doping rare earth elements is a promising way to improve the performances of lead halide perovskites. In this paper, we review the latest research progress of rare earths doped lead halide perovskite materials in the preparation, structures, properties, as well as radiation detectors. The doped rare earths introduce new luminescent centers and energy levels for new luminescence properties, improving the crystallinity and semiconductor performances of perovskite crystals. Therefore, rare earth doping can further improve the performance of lead halide perovskite radiation detectors.
1 Introduction
2 Growth and structure of rare earth doped lead halides perovskites
2.1 rare earth ions and Rare earth doped lead halides perovskites
2.2 Synthesis of rare earth-doped lead halides perovskites
2.3 Effect of rare earth ions on the growth and structure of perovskite
2.4 Composition distribution and doping sites of rare earth ions in lead halide perovskite
3 Luminescence properties of rare earth doped lead halides perovskites
3.1 Introducing the luminous centers of rare earth ions
3.2 Enhanced emission of perovskite matrix
4 Semiconductor electrical properties of rare earth doped lead halides perovskites
4.1 Theoretical study on electrical doping of lead perovskite halide by rare earth ions
4.2 Experimental study on electrical doping of lead perovskite halide by rare earth ions
5 Application of rare earth Ions doped lead halides perovskite crystals in radiation detection
5.1 Brief introduction of perovskite radiation detection
5.2 Rare earth doped lead perovskite halide radiation radiation detector
6 Conclusion and prospect
lead halide perovskites / rare earth doping / photoluminescence / radiation detection
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