
Metal-Organic Frameworks and Their Derivative Nano Anode Materials
Haotian Ma, Rujin Tian, Zhongsheng Wen
Prog Chem ›› 2023, Vol. 35 ›› Issue (12) : 1807-1846.
Metal-Organic Frameworks and Their Derivative Nano Anode Materials
Anode is one of the important components for lithium ion battery. Many technical bottlenecks (such as lower ionic-electronic conductivity, huge volume effect and easy pulverization resulted from long-term charge/discharge process) prevent the development and large scale application of traditional anode materials. As a novel kind of advanced multi-functional materials, Metal-organic frameworks (MOFs) and their derivative materials behave enough pore structures promoting rapid migration of Li+ and electron, and high specific surface areas providing abundant active sites for electrochemical reaction. Importantly, tunable structure and chemical composition of the MOFs and their derivative materials can be further optimized by changing parameters of synthesis process, thereby markedly increases specific capacity and cycle stability of lithium ion batteries. Herein, the recent progress in the MOFs and their derivative materials used as anode for lithium ion batteries are reviewed systematically, and the relationships between their preparation methods, microstructures, morphologies and corresponding electrochemical properties are summarized detailly. The urgent problems and challenges of this class of anode materials for lithium ion batteries are also analyzed. On the basis of resonable choosing organic ligands and metal centers, some effective measures for improving performances of lithium storage are proposed by combining with the variability and particularity of structure of the MOFs and their derivative materials, and the feasible strategies for commercialization application are suggested. Finally, the perspective and future development in design and fabrication of the new types of nano porous anodes with high energy efficiencies in relation with the next generation lithium ion battery are further discussed.
1 Introduction
1.1 Conversion mechanism
1.2 Insertion/extraction mechanism
1.3 Absorption/desorption mechanism
2 Pristine MOFs
2.1 Co-MOFs
2.2 Zn-MOFs
2.3 Mn-MOFs
2.4 Fe-MOFs
2.5 Ni-MOFs
2.6 Cu-MOFs
2.7 Sn-MOFs
2.8 Other metal-based MOFs
3 MOFs-derived metal compounds
3.1 Monometal oxides
3.2 Bimetal oxides
3.3 Other metal compounds
4 MOFs-derived porous carbon
5 MOFs-derived composites
5.1 MOFs/metal compounds
5.2 MOFs/carbon-based materials
5.3 metal oxide/Metal oxide
5.4 Metal oxide/carbon-based materials
5.5 Metal sulfide/carbon-based materials
5.6 Other metal compound/carbon-based materials
5.7 metal/metal oxide/carbon-based materials
6 Conclusion and outlook
lithium ion battery / anode / metal-organic frameworks / derivative materials
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