Application of MOFs in Catalytic Conversion of Organic Molecules

Xichen Li; Zheng Li; Can Peng; Chen Qian; Yufei Han; Tao Zhang

doi:10.7536/PC230718

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Prog Chem ›› 2024, Vol. 36 ›› Issue (3) : 367-375. DOI: 10.7536/PC230718

Review

Application of MOFs in Catalytic Conversion of Organic Molecules

Xichen Li ¹^,² ,
Zheng Li ¹^,² ,
Can Peng ¹^,² ,
Chen Qian ¹^,² ,
Yufei Han ¹^,² ,
Tao Zhang ¹^,²^,^*

Author information +

History +

Abstract

Metal-organic framework compounds (MOF), also known as porous coordination polymers, are a new type of organic-inorganic hybrid porous materials which are self-assembled from organic ligands and metal ions, and are an important part of nanomaterials. Compared to other porous materials, MOFs have a large surface area, high porosity and adjustable structure and properties, making them have a good application prospect in heterogeneous catalysis. In this paper, the background of MOFs catalysis is briefly reviewed, followed by a review and prospect of the recent progress of MOFs in catalytic conversion reactions of organic molecules, in order to provide a reference for the design and development of organic reactions catalyzed by MOFs.

Contents

1 Introduction

2 Knoevenagel Condensation catalyzed by MOFs

3 Suzuki-Miyaura Reaction catalyzed by MOFs

4 Mizoroki-Heck Reaction catalyzed by MOFs

5 Aldol Condensation catalyzed by MOFs

6 A³-Coupling Reaction catalyzed by MOFs

7 Cycloaddition of CO₂catalyzed by MOFs

8 Oxidation and reduction of unsaturated hydrocarbons catalyzed by MOFs

9 Conclusion and outlook

Key words

metal-organic framework / heterogeneous catalysis / interfacial organometallic chemistry / organic molecules / high value-added chemicals

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Xichen Li , Zheng Li , Can Peng , et al . Application of MOFs in Catalytic Conversion of Organic Molecules[J]. Progress in Chemistry. 2024, 36(3): 367-375 https://doi.org/10.7536/PC230718

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Funding

National Natural Science Foundation of China(12275135)

Jiangsu Province University Natural Science Research Project(21KJB350015)

Nanjing Medical University Talent Introduction Research Start-up Fund(NMUR20210003)

Key Project of Connotation Construction of Nanjing Medical University and Science and Technology Development Fund of Nanjing Medical University(NMUB20210014)

Jiangsu Province University Natural Science Research Project(22KJB350008)