Application of Copper-Based Catalysts for the Selective Catalytic Combustion of Ammonia

Qian Zhang; Runze Tao; Yu Huang; Houzhang Tan; Baochong Cui

doi:10.7536/PC230816

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Prog Chem ›› 2024, Vol. 36 ›› Issue (5) : 783-797. DOI: 10.7536/PC230816

Review

Application of Copper-Based Catalysts for the Selective Catalytic Combustion of Ammonia

Qian Zhang ¹^,³^,^* ,
Runze Tao ¹^,² ,
Yu Huang ¹ ,
Houzhang Tan ²^,^* ,
Baochong Cui ²

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Abstract

Ammonia is a promising new energy carrier that has the potential to replace traditional fossil fuels due to its high calorific value,CO₂emission-free and renewable properties,and low storage and transportation costs.However,ammonia combustion faces several challenges,such as high NO_xemission,slow combustion rate,and ignition difficulties.To address these challenges,selective catalytic combustion is an efficient and promising way that can decrease combustion temperature,enhance combustion stability,improve fuel conversion rate and reduce NO_xemission while requiring less auxiliary fuel and consuming less energy.Copper-based catalysts are cost-effective and they are demonstrated to exhibit excellent performance in ammonia catalytic combustion with high N₂selectivity.In this review,the reaction experimental setup and primary mechanisms,namely NH-HNO,N₂H₄and i-SCR pathways,are presented first;then,the recent research progress on copper-based supported catalysts for ammonia combustion,including the effect of preparation methods,types of support materials,metal-support interactions,and Cu-based single or multiple active components on catalytic performance are reviewed in detail.Finally,the review is concluded by summarizing the research achievements,current drawbacks and proposing the future developments 。

Contents

1 Introduction

2 Catalytic NH₃combustion experimental setup and mechanisms

2.1 Experimental setup and performance indicators

2.2 Mechanism and research techniques

3 Copper-based catalysts for NH₃combustion

3.1 The effect of preparation methods on performance

3.2 The effect of support on performance

3.3 The effect of active component on performance

4 Conclusion and outlook

Key words

new energy carrier / ammonia / copper based catalysts / selective catalytic combustion / NO_x emission

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Qian Zhang , Runze Tao , Yu Huang , et al . Application of Copper-Based Catalysts for the Selective Catalytic Combustion of Ammonia[J]. Progress in Chemistry. 2024, 36(5): 783-797 https://doi.org/10.7536/PC230816

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