Research progress in preparation and application of high-color-purity fluorescent carbon dots

Yanan LI, Yun LIU, Chunyan LIU, Junping XIAO

Journal of Materials Engineering ›› 2023, Vol. 51 ›› Issue (11) : 14-22.

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Journal of Materials Engineering ›› 2023, Vol. 51 ›› Issue (11) : 14-22. DOI: 10.11868/j.issn.1001-4381.2022.000980
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Research progress in preparation and application of high-color-purity fluorescent carbon dots

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Abstract

Narrow-band,high-color-purity luminescent materials are widely used in the fields of ultra-high-definition display and lighting,super-resolution imaging and sensing,bio-imaging and anti-counterfeiting. However,the high-color-purity fluorescent materials mainly used are Ⅱ-Ⅳ semiconductor quantum dots,halide perovskite nanocrystals and so on,which generally contains highly toxic transition metal ions such as Cd and Pb. Moreover,these materials often show low environmental stability. In contrast,carbon dots have many advantages including no heavy metal ions,high photo/chemical stability,low toxicity and wide source of raw materials. Therefore, developing fluorescent carbon dots with high-color-purity has important theoretical and practical significance. Here,the research progress of the synthesis and application of high-color-purity carbon dots was reviewed;the effects of precursor,synthetic methods and some factors on the position and the full width at half maximum of the carbon dots and the application in the field of LED, sensing and imaging were discussed. Additionally,the opportunities and challenges of high-color-purity carbon dots in large-scale synthesis,optical properties including the tune of PL position,the enhancement of the fluorescent quantum yield and color purity,understanding their photoluminescence mechanism as well as developing new applications were proposed.

Key words

high-color-purity / carbon dots / preparation / application

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Yanan LI , Yun LIU , Chunyan LIU , et al. Research progress in preparation and application of high-color-purity fluorescent carbon dots[J]. Journal of Materials Engineering. 2023, 51(11): 14-22 https://doi.org/10.11868/j.issn.1001-4381.2022.000980

References

1
BAI M J LIU X H SAKAI N,et al. General synthesis of layered rare-earth hydroxides (RE=Sm,Eu,Gd,Tb,Dy,Ho,Er,Y) and direct exfoliation into monolayer nanosheets with high color purity[J]. The Journal of Physical Chemistry Letters202112(41):10135-10143.
2
WANG W TAO M X LIU Y X,et al. Photoluminescence control of UCr4C4-type phosphors with superior luminous efficiency and high color purity via controlling site selection of Eu2+ activators[J]. Chemistry of Materials201931(21): 9200-9210.
3
LIU T G CHENG C LOU W W, et al. Ultrapure blue organic light-emitting diodes exhibiting 13 nm full width at half-maximum[J]. Journal of Materials Chemistry C202210(20):7799-7802.
4
PARK H J JANG J H LEE J H,et al. Highly efficient deep-blue phosphorescent OLEDs based on a trimethylsilyl-substituted tetradentate Pt(Ⅱ) complex[J]. ACS Applied Materials & Interfaces202214(30):34901-34908.
5
LEE H LEE S.Gram-scale synthesis of core-gradient shell CdSe/Cd1- x Zn x Se1- y S y /ZnS quantum dots with R/G/B emission using eco-friendly hydrolyzed cooking oils:implications for display applications[J].ACS Applied Nano Materials20214(11):11573-11581.
6
TAYLOR D A TEKU J A CHO S,et al. Importance of surface functionalization and purification for narrow FWHM and bright green-emitting InP core-multishell quantum dots via a two-step growth process[J]. Chemistry of Materials202133(12): 4399-4407.
7
PADHIAR M A WANG M JI Y,et al. Stable CsPbX3(Br/Cl) perovskite nanocrystal layer passivated with Al-doped CdSe for blue light-emitting diodes[J]. ACS Applied Nano Materials20225(1):908-916.
8
YANG J N CHEN T GE J,et al. High color purity and efficient green light-emitting diode using perovskite nanocrystals with the size overly exceeding bohr exciton diameter[J]. Journal of the American Chemical Society2021143(47):19928-19937.
9
HU C MU Y LI M Y,et al. Recent advances in the synthesis and applications of carbon dots[J]. Acta Physico-Chimica Sinica201935(6):572-590.
10
GUO H Z WEN S K LI W T,et al. A universal strategy to separate hydrophilic hybrid-light carbon quantum dots using pure water as eluent[J]. Applied Materials Today202018:100528-100534.
11
WANG Z DONG X Z ZHOU S Y,et al. Ultra-narrow-bandwidth graphene quantum dots for superresolved spectral and spatial sensing[J]. NPG Asia Materials202113(1):1-13.
12
LIU J J GENG Y J LI D W,et al. Deep red emissive carbonized polymer dots with unprecedented narrow full width at half maximum[J]. Advanced Materials202032(17):1906641-1906649.
13
LIU J J LI R YANG B. Carbon dots: a new type of carbon-based nanomaterial with wide applications[J]. ACS Central Science20206(12):2179-2195.
14
刘兴华,王军丽,王亚玲,等. 多色荧光碳点调控及其应用[J]. 材料工程202048(4):36-45.
LIU X H WANG J L WANG Y L,et al. Adjusting of multicolor fluorescence carbon dots and their application[J]. Journal of Materials Engineering202048(4):36-45.
15
YOON H KIM H S KIM J,et al. Blue graphene quantum dots with high color purity by controlling subdomain formation for light-emitting devices[J]. ACS Applied Nano Materials20203(7):6469-6477.
16
ZHAI Y P ZHANG B W SHI R,et al. Carbon dots as new building blocks for electrochemical energy storage and electrocatalysis[J]. Advanced Energy Materials202212(6):2103426-2103461.
17
王林鹏,马玉洁,周学华,等. 碳点的制备与应用研究进展[J]. 材料工程201543(5):101-112.
WANG L P MA Y J ZHOU X H,et al. Progress in research on preparation and application of carbon dots[J]. Journal of Materials Engineering201543(5):101-112.
18
KWON W KIM Y H LEE C L,et al. Electroluminescence from graphene quantum dots prepared by amidative cutting of tattered graphite[J]. Nano Letters201414(3):1306-1311.
19
CHEN W LI F S WU C X,et al. Optical properties of fluorescent zigzag graphene quantum dots derived from multi-walled carbon nanotubes[J].Applied Physics Letters2014104(6):63109-63113.
20
ZHANG Y T LI K K REN S Z,et al. Coal-derived graphene quantum dots produced by ultrasonic physical tailoring and their capacity for Cu(Ⅱ) detection[J]. ACS Sustainable Chemistry & Engineering20197(11):9793-9799.
21
WANG B Y CAI H J WATERHOUSE G I N,et al. Carbon dots in bioimaging, biosensing and therapeutics: a comprehensive review[J]. Small Science20222(6): 2200012-2200038.
22
KUMARI R,PAL K, KARMAKAR P,et al. pH-responsive Mn-doped carbon dots for white-light-emitting diodes, fingerprinting,and bioimaging[J]. ACS Applied Nano Materials20192(9):5900-5909.
23
SHANI B Z SATHISH R SUSANTA K B,et al. Resveratrol carbon dots disrupt mitochondrial function in cancer cells[J]. Bioconjugate Chemistry202233(9):1663-1671.
24
LI T Z SHI W,E S,et al. Green preparation of carbon dots with different surface states simultaneously at room temperature and their sensing applications[J]. Journal of Colloid and Interface Science2021591:334-342.
25
CHEN Y Y WANG C XU Y L. Red emissive carbon dots obtained from direct calcination of 1,2,4-triaminobenzene for dual-mode pH sensing in living cells[J]. New Journal of Chemistry202044(17):7210-7214.
26
SAINI D AGGARWALI R SONKER A K,et al. Photodegradation of azo dyes in sunlight promoted by nitrogen-sulfur-phosphorus codoped carbon dots[J]. ACS Applied Nano Materials20214(9):9303-9312.
27
CHEN Y J YANG Q XU P P,et al. One-step synthesis of acidophilic highly-photoluminescent carbon dots modified by ionic liquid from polyethylene glycol[J]. ACS Omega20172(8):5251-5259.
28
WAREING T C GENTILE P PHAN A N. Biomass-based carbon dots:current development and future perspectives[J]. ACS Nano202115(10):15471-15501.
29
JINDAL S ANAND R SHARMA N,et al. Sustainable approach for developing graphene-based materials from natural resources and biowastes for electronic applications[J]. ACS Applied Electronic Materials20224(5):2146-2174.
30
YUAN F L YUAN T SUI L Z,et al. Engineering triangular carbon quantum dots with unprecedented narrow bandwidth emission for multicolored LEDs[J]. Nature Communications20189(1):2211-2249.
31
YUAN F L HE P XI Z F,et al. Highly efficient and stable white LEDs based on pure red narrow bandwidth emission triangular carbon quantum dots for wide-color gamut backlight displays[J]. Nano Research201912(7):1669-1674.
32
YOSHINAGA T SHINODA M,ISO Y, et al. Glycothermally synthesized carbon dots with narrow-bandwidth and color-tunable solvatochromic fluorescence for wide-color-gamut displays[J]. ACS Omega20216(2):1741-1750.
33
KWAK B E YOO H J KIM D H. Encapsulation of carbon dots in silica matrices offers narrow emission in the solid-state of printed fluorescent inks[J]. ACS Applied Nano Materials20214(9):9497-9507.
34
HE F T BAI J CHENG Y Y,et al. Insights into fluorophores of dual-emissive carbon dots derived by naphthalenediol solvothermal synthesis[J]. The Journal of Physical Chemistry C2021125(9):5207-5216.
35
LIU J J LI D W ZHANG K,et al. One-step hydrothermal synthesis of nitrogen-doped conjugated carbonized polymer dots with 31% efficient red emission for in vivo imaging[J]. Small201814(15):1703919-1703928.
36
ZHANG Q WANG R Y FENG B W,et al. Photoluminescence mechanism of carbon dots:triggering high-color-purity red fluorescence emission through edge amino protonation[J]. Nature Communications202112(1): 6586-6599.
37
RU Y SUI L Z SONG H Q,et al. Rational design of multicolor‐emitting chiral carbonized polymer dots for full‐color and white circularly polarized luminescence[J]. Angewandte Chemie International Edition202160(25):14091-14099.
38
ZHANG D Y CHAO D Y YU C Y,et al. One-step green solvothermal synthesis of full-color carbon quantum dots based on a doping strategy[J]. The Journal of Physical Chemistry Letters202112(37):8939-8946.
39
GAN J WU Y YANG F,et al. UV-filtering cellulose nanocrystal/carbon quantum dot composite films for light conversion in glass windows[J]. ACS Applied Nano Materials20214(11):12552-12560.
40
XU J H LIANG Q J LI Z J,et al. Rational synthesis of solid‐state ultraviolet B emitting carbon dots via acetic acid‐promoted fractions of sp3 bonding strategy[J]. Advanced Materials202234(17):2200011-2200019.
41
CHENG T Y CHOU F P HUANG S C,et al. Electroluminescence and photocatalytic hydrogen evolution of S,N co-doped graphene oxide quantum dots[J]. Journal of Materials Chemistry A20221(7):3650-3658.
42
HAN Z X NI Y Q REN J K,et al. Highly efficient and ultra-narrow bandwidth orange emissive carbon dots for microcavity lasers[J]. Nanoscale201911(24):11577-11583.
43
YUAN F L WANG Y K SHAARMA G, et al. Bright high-colour-purity deep-blue carbon dot light-emitting diodes via efficient edge amination[J].Nature Photonics202014(3):171-176.
44
LIU Y F GOU H L HUANG X,et al. Rational synthesis of highly efficient ultra-narrow red-emitting carbon quantum dots for NIR-Ⅱ two-photon bioimaging[J].Nanoscale202012(3):1589-1601.
45
TONG L L WANG X X CHEN Z Z, et al. One-step fabrication of functional carbon dots with 90% fluorescence quantum yield for long-term lysosome imaging[J]. Analytical Chemistry202092(9):6430-6436.
46
LIU Y LIU C Y ZHANG Z Y. Graphitized carbon dots emitting strong green photoluminescence[J]. Journal of Materials Chemistry C20131(32):4902-4907.
47
PAN L L SUN S ZHANG L, et al. Near-infrared emissive carbon dots for two-photon fluorescence bioimaging[J]. Nanoscale20168(39):17350-17356.
48
WANG X ZHANG X Y GU X Q, et al. A bright and stable violet carbon dot light‐emitting diode[J]. Advanced Optical Materials20208(15):2000239-2000246.
49
LIU J KONG T XIONG H M. Mulberry leaves derived red emissive carbon dots for feeding silkworms to produce brightly fluorescent silk[J].Advanced Materials202234(16): 2200152-2200160.
50
QU Y T LI D N LIU J R,et al. Magnolia denudata leaf-derived near-infrared carbon dots as fluorescent nanoprobes for palladium(Ⅱ) detection and cell imaging[J].Microchemical Journal2022178:107375-107381.
51
RAO H B LIU W HE K Q,et al. Smartphone-based fluorescence detection of Al3+ and H2O based on the use of dual-emission biomass carbon dots[J]. ACS Sustainable Chemistry & Engineering20208(23):8857-8867.
52
GUO J Z LI H LING L T,et al. Green synthesis of carbon dots toward anti-counterfeiting[J]. ACS Sustainable Chemistry & Engineering20208(3):1566-1572.
53
MOU Z H YANG Q B ZHAO B,et al. Scalable and sustainable synthesis of carbon dots from biomass as efficient friction modifiers for polyethylene glycol synthetic oil[J]. ACS Sustainable Chemistry & Engineering20219(44): 14997-15007.
54
TONG X ZHU Y F TONG C Y,et al. Simultaneous sensing γ-glutamyl transpeptidase and alkaline phosphatase by robust dual-emission carbon dots[J].Analytica Chimica Acta20211178:338829.
55
ATCHUDAN R JEBAKUMAR I E THOMAS N,et al. Sustainable synthesis of carbon quantum dots from banana peel waste using hydrothermal process for in vivo bioimaging[J]. Physica E2021126:114417-114424.
56
BOOBALAN T SETHUPATHI M SENGOTTUVELAN N, et al. Mushroom-derived carbon dots for toxic metal ion detection and as antibacterial and anticancer agents[J]. ACS Applied Nano Materials20203(6):5910-5919.
57
LU H Z LI C C WANG H H,et al. Biomass-derived sulfur, nitrogen Co-doped carbon dots for colorimetric and fluorescent dual mode detection of silver (Ⅰ) and cell imaging[J].ACS Omega20194(25):21500-21508.
58
SU R N WANG D LIU M,et al. Subgram-scale synthesis of biomass waste-derived fluorescent carbon dots in subcritical water for bioimaging, sensing, and solid-state patterning[J]. ACS Omega20183(10):13211-13218.
59
LU W B QIN X Y LIU S,et al. Economical, green synthesis of fluorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(Ⅱ) ions[J]. Analytical Chemistry201284(12):5351-5357.
60
PANDIYAN S ARUMUGAM L SRIRENGAN S P,et al. Biocompatible carbon quantum dots derived from sugarcane industrial wastes for effective nonlinear optical behavior and antimicrobial activity applications[J]. ACS Omega20205(47): 30363-30372.
61
TAI J Y LEONG K H SARAVANAN P,et al. Facile green synthesis of fingernails derived carbon quantum dots for Cu2+ sensing and photodegradation of 2,4-dichlorophenol[J]. Journal of Environmental Chemical Engineering20219(1): 104622-104631.
62
邹漫, 陈叶青. 碳点在生物诊疗中的应用[J]. 材料工程202048(9):59-68.
ZOU M CHEN Y Q. Application of carbon dots in biological diagnosis and treatment[J]. Journal of Materials Engineering202048(9):59-68.
63
张长波,向文柔,田丰玲,等.单激发双发射氮掺杂量子点的制备及其在生物成像和荧光油墨中的应用[J].贵林师范大学学报(自然科学版)202240(4):7-14.
ZHANG C B HE W R TIAN F L,et al.Preparation of nitrogendoped carbon quantum dots with single excited double emission and their applications for bioimaging and fluorescent ink[J].Journal of Guizhou Normal University(Natural Sciences)202240(4):7-14.
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