Design and Applications of Carborane-Based Luminescent Materials

Qing Jiang, Xinyi Li, Yunjun Shen, Yuzhen Zhang

Prog Chem ›› 2026, Vol. 38 ›› Issue (6) : 1073-1084.

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Abbreviation (ISO4): Prog Chem      Editor in chief: Jincai ZHAO

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Prog Chem ›› 2026, Vol. 38 ›› Issue (6) : 1073-1084. DOI: 10.7536/PC20251011
Review

Design and Applications of Carborane-Based Luminescent Materials

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Abstract

Cage-like carboranes,with their unique polyhedral spatial architecture and three-dimensional(3D)delocalized electron system,are regarded as 3D analogs of benzene rings and exhibit 3D aromaticity that is not found in classical two-dimensional(2D)aromatic systems. These compounds generally possess high chemical stability,high thermal stability,and excellent biocompatibility,endowing them with broad application prospects in the fields such as organic optoelectronic materials and biomedicine. This article systematically reviews the significant research progress achieved in recent years regarding carborane-based luminescent materials,focusing on aspects such as molecular design strategies and application field. In terms of molecular design,researchers have effectively regulated the aggregated structure,charge transfer properties,and excited-state characteristics of molecules by means of embedding carborane cages into conjugated backbones,using them as pendant groups,or employing them to construct donor-acceptor(D-A)systems. This regulation,in turn,enables the enhancement of luminescent quantum yield and the tuning of emission wavelength ranges. In the field of applications,this class of materials not only demonstrates great potential in high-performance optoelectronic materials but also exhibits prominent application value in fields such as circularly polarized luminescence(CPL),stimuli-responsive materials,and bioimaging. Finally,the article provides an outlook on the challenges and development prospects for the future development of this category of materials.

Contents

1 Introduction

2 o-Carborane based luminescent materials

2.1 o-Carborane C2B10H12 based organic luminescent materials

2.2 o-Carborane C2B10H12 based metal complex luminescent materials

3 Carborane anion luminescent materials

3.1 nido-Carborane anion [nido-C2B9H12]⁻ based luminescent materials

3.2 Monocarba-closo-dodecaborate anion [CB11H12]⁻ luminescent materials

4 Conclusion and outlook

Key words

luminescent material / carborane / synthesis / photophysical property / functional application

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Qing Jiang , Xinyi Li , Yunjun Shen , et al. Design and Applications of Carborane-Based Luminescent Materials[J]. Progress in Chemistry. 2026, 38(6): 1073-1084 https://doi.org/10.7536/PC20251011

References

[1]
Yuhara K, Tanaka K. Angew. Chem., 2024, 136(15): e202319712.
[2]
Wang L, Zhou C S, Dai Y H, Hou Y L, Yan J F, Li Y M, Yuan Y F. ChemistrySelect, 2023, 8(1): e202204063.
[3]
Wang D, Wang G, Liu K, Li J, Wang Z L, Liu J, Ding L P, Miao R, Fang Y. Chin. Chemical Lett., 2022, 33(5): 2532.
[4]
Yuhara K, Tanaka K. Chem. Sci., 2025, 16(15): 6495.
[5]
Li J F, Shi S N, Deng Y H, Ma J M, Wu W, Chen Y, Yan Y, Lai W Y. J. Mater. Chem. C, 2024, 12(42): 17270.
[6]
Wang Z J, Zhao J W, Muddassir M, Guan R F, Tao S L. Inorg. Chem., 2021, 60(7): 4705.
[7]
Yanagihara T, Tanaka K. Adv. Opt. Mater., 2023, 11(18): 2300492.
[8]
Zhao W J, He J J, Lu C S. Univ. Chem., 2019, 34(1): 39.
(赵薇佳, 贺嘉俊, 芦昌盛. 大学化学, 2019, 34(1): 39.)
[9]
Szathmári B, Hessz D, Zámbó D, Bruhn C, Pietschnig R, Udvardy A, Szabó P, Holczbauer T, Balogh M J, Kelemen Z. Chem., 2025, 31(16): e202404462.
[10]
Li N, Wu X Y, Lv Y, Chi J X, Guo J X. New J. Chem., 2025, 49(25): 10530.
[11]
Wu L, Holzapfel M, Schmiedel A, Peng F W, Moos M, Mentzel P, Shi J Q, Neubert T, Bertermann R, Finze M, Fox M A, Lambert C, Ji L. Nat. Commun., 2024, 15: 3005.
[12]
Li J, Peng L Y, Lin S M, Wang X B, Miao R, Fang Y. J. Phys. Chem. Lett., 2024, 15(36): 9247.
[13]
Nguyen N N T, Lutfi R M, Lee T, Jung J, Lee M H. Inorg. Chem. Front., 2025, 12(14): 4503.
[14]
Li Z N, Zhang Q, Sun F X, Lv C Y, Meng X M, Hu Y, Xu D Q, Li C J, Li L, Wang K, Zhang Y J. Adv. Sci., 2025, 12(11): 2411765.
[15]
Zhang H, Zhao X Q, Nie Y. In Proceedings of the 8th National Conference on Physical Inorganic Chemistry, Chinese Chemical Society (Part I). Taiyuan: The Chemical Society of China National Natural Science Foundation of China, 2018, 122.
(张昊, 赵晓青, 聂永. 中国化学会第八届全国物理无机化学学术会议论文集(一). 太原: 中国化学会, 国家自然科学基金委员会, 2018, 122.)
[16]
Chen Y, Wu W, Zhang L M, Li J F. Guangzhou Chem., 2025, 50(3): 20.
(陈雨, 武伟, 张丽敏, 李军峰. 广州化学, 2025, 50(3): 20.)
[17]
Kim S, You D K, Kim N, Shin I, Kim D, Lee K M. Dalton Trans., 2025, 54(3): 1164.
[18]
Li J F, Zhang L M, Zhao S J, Li Y J, Wang T, Gao M, Deng Y H, Shi S N. J. Mater. Chem. C, 2025, 13(23): 11979.
[19]
Kim S, Lee J H, So H, Kim M, Mun M S, Hwang H, Park M H, Lee K M. Inorg. Chem. Front., 2020, 7(16): 2949.
[20]
Smyshliaeva L A, Varaksin M V, Fomina E I, Medvedeva M V, Svalova T S, Kozitsina A N, Demidov O P, Borovlev I V, Mensch C, Mampuys P, Maes B U W, Charushin V N, Chupakhin O N. Organometallics, 2021, 40(16): 2792.
[21]
Yang H Y, Liu H C, Shen Y X, Zhang S T, Zhang Q, Song Q B, Lv C Y, Zhang C, Yang B, Ma Y G, Zhang Y J. Angew. Chem. Int. Ed., 2022, 61(16): e202115551.
[22]
Lee T, Jang J H, Nguyen N N T, Jung J, Lee J H, Lee M H. Adv. Sci., 2024, 11(11): 2309016.
[23]
Shao Y T, Huang R R, Luo Y, Wei H X, Peng H N, Fang Y. Sens. Actuat. B Chem., 2024, 418: 136285.
[24]
Sun Z F, Zong J B, Ren H Y, Lu C S, Tu D S, Poater J, Solà M, Shi Z Z, Yan H. Nat. Commun., 2024, 15: 7934.
[25]
Nan L F, He P, Zhang T W, Dong Y R, Feng C, He T, Li P F, Zhang Y F, Nie Y, Jiao J. J. Am. Chem. Soc., 2025, 147(28): 24430.
[26]
Jin X P, Wu X Y, Lyu Y, Xinjiang Univ. Nat. Sci. Ed. Chin. Engl., 2022, 39(4): 446.
靳小平, 吴雪岩, 吕燕, 郭继玺. 新疆大学学报(自然科学版)(中英文), 2022, 39(4): 446.)
[27]
Yan P Z, Gao S L, Li T R, Miao J L, Jiang X C, Nie Y. Chin. J. Org. Chem., 2025, 45(8): 2677.
(闫鹏泽, 高淑莉, 李天瑞, 苗金玲, 蒋绪川, 聂永. 有机化学, 2025, 45(8): 2677.)
[28]
Yan H, Tu D S. In Proceedings of the 8th National Conference on Physical Inorganic Chemistry, Chinese Chemical Society (Part I). Taiyuan: The Chemical Society of China, National Natural Science Foundation of China, 2018, 262.
(燕红, 涂德双. 中国化学会第八届全国物理无机化学学术会议论文集(二). 太原: 中国化学会, 国家自然科学基金委员会, 2018, 262.)
[29]
Wu X Y, Guo J X, Lv Y, Jia D Z, Zhao J Z, Shan H C, Jin X P, Ma Y D. Mater. Chem. Front., 2020, 4(1): 257.
[30]
Sinha S, Kelemen Z, Hümpfner E, Ratera I, Malval J P, Jurado J P, Viñas C, Teixidor F, Núñez R. Chem. Commun., 2022, 58(25): 4016.
[31]
Xu C Y, Li T R, Miao J L, Liu K X, Nie Y, Liu G N, Jiang X C. New J. Chem., 2023, 47(9): 4448.
[32]
Li T R, Zhang H, Miao J L, Xu C Y, Nie Y, Liu G N, Sun G X, Jiang X C. New J. Chem., 2023, 47(39): 18243.
[33]
Wang L, Chen R J, Yan J F, Yuan Y F. New J. Chem., 2023, 47(34): 16129.
[34]
Xu X Y, Zhao X Y, Xu S, Zhang X N, Wang Q H, Wu L, Li X, Shi J Q, Ma J N, Ji L, Huang W. Angew. Chem. Int. Ed., 2025, 64(51): e21735.
[35]
Ji L, Riese S, Schmiedel A, Holzapfel M, Fest M, Nitsch J, Curchod B F E, Friedrich A, Wu L, Al Mamari H H, Hammer S, Pflaum J, Fox M A, Tozer D J, Finze M, Lambert C, Marder T B. Chem. Sci., 2022, 13(18): 5205.
[36]
Zhao X Y, Zhang X N, Li X, Wu L, Ji L. Chem. Eur. J., 2024, 30(35): e202401246.
[37]
Zaitsev A V, Kononova E G, Markova A A, Shibaeva A V, Kostyukov A A, Egorov A E, Kuzmin V A, Shtil A A, Ol’shevskaya V A. Dyes Pigm., 2022, 207: 110711.
[38]
Ma W L, Zhang J Y, Zong J B, Ren H Y, Tu D S, Xu Q F, Tang B Z, Yan H. Angew. Chem., 2024, 136(52): e202410430.
[39]
Shi J Q, Li M J, Xu S J, Chen M H, Zhang X N, Zhang Y F, Wu L, Ji L. Cryst. Growth Des., 2024, 24(22): 9440.
[40]
Soldevila-Sanmartín J, Ruiz E, Choquesillo-Lazarte D, Light M E, Viñas C, Teixidor F, Núñez R, Pons J, Planas J G. J. Mater. Chem. C, 2021, 9(24): 7643.
[41]
Alconchel A, Crespo O, Gimeno M C. Inorg. Chem., 2023, 62(26): 10431.
[42]
Ferraro V, Bizzarri C, Bräse S. Adv. Sci., 2024, 11(34): 2404866.
[43]
Yao Z J, Jin Y X, Deng W, Liu Z J. Inorg. Chem., 2021, 60(4): 2756.
[44]
Conway-Kenny R, Ferrer-Ugalde A, Careta O, Cui X N, Zhao J Z, Nogués C, Núñez R, Cabrera-González J, Draper S M. Biomater. Sci., 2021, 9(16): 5691.
[45]
Alpatova V M, Nguyen M T, Rys E G, Liklikadze G K, Kononova E G, Smol’yakov A F, Borisov Y A, Egorov A E, Kostyukov A A, Shibaeva A V, Burtsev I D, Peregudov A S, Kuzmin V A, Shtil A A, Markova A A, Ol’shevskaya V A. Biomater. Sci., 2025, 13(3): 711.
[46]
Lee L C, Lo K K. J. Am. Chem. Soc., 2022, 144(32): 14420.
[47]
Powley S L, Riley C, Cho H H, Le Phuoc N, Linnolahti M, Greenham N, Romanov A S. Chem. Commun., 2023, 59(80): 12035.
[48]
Alconchel A, Crespo O, García-Orduña P, Gimeno M C. Inorg. Chem., 2021, 60(23): 18521.
[49]
Sujith S, Lee M H. Bull. Korean Chem. Soc., 2021, 42(1): 43.
[50]
Ochi J, Tanaka K, Chujo Y. Angew. Chem., 2020, 132(25): 9925.
[51]
Ouyang H Z, Wang Z, Liu M. PLoS One, 2024, 19(12): e0313661.
[52]
Sujith S, Nam E B, Lee J, Lee S U, Lee M H. Inorg. Chem. Front., 2020, 7(18): 3456.
[53]
Uemura K, Tanaka K, Chujo Y. Crystals, 2022, 12(5): 688.
[54]
Kim M, Im S, Ryu C H, Lee S H, Hong J H, Lee K M. Dalton Trans., 2021, 50(9): 3207.
[55]
Li Q X, Shi C, Huang M L, Zhang X H, Sun F X, Zheng Y, Yan H, Yang C L, Yuan A H. Dalton Trans., 2021, 50(44): 16304.
[56]
Cao J, Jin T, Shao S H, Mao B N, Feng J. Front. Chem., 2024, 12: 1402640.
[57]
Wang L, Mao L W, Feng X B, Wang S, Jin G F. Front. Chem., 2024, 12: 1389694.
[58]
Zhou M, Jin T, Liu Y, Wang S, Feng J K, Shao S H, Lu C C, Jin G F. J. Mol. Struct., 2024, 1299: 137211.
[59]
Jin L, Shen Y J, Qiu H, Zhang Y Z, Bian H D. Appl. Organomet. Chem., 2024, 38(11): e7680.
[60]
Sun W Q, Jin Y J, Wang Y T, Wen Z Y, Sun J Z, Yao J, Duttwyler S, Li H R. Chem. Sci., 2025, 16(14): 5942.
[61]
Shen Y J, Kong X J, Yang F J, Bian H D, Cheng G, Cook T R, Zhang Y Z. Inorg. Chem., 2022, 61(42): 16707.
[62]
Yang R H, Zhou Y, Bian H D, Cheng G, Zhang Y Z, Che C M, Cook T R, Shen Y J. Chem. Eng. J., 2022, 447: 137432.
[63]
Kong X J, Shen Y J, Bian H D, Zhang Y Z. Dalton Trans., 2023, 52(11): 3249.
[64]
Peng Z X, Zhang K, Huang Z W, Wang Z B, Duttwyler S, Wang Y G, Lu P. J. Mater. Chem. C, 2019, 7(8): 2430.
[65]
Zhang K, Shen Y J, Yang X L, Liu J Y, Jiang T, Finney N, Spingler B, Duttwyler S. Chem., 2019, 25(37): 8754.

Funding

Guangxi Natural Science Foundation(2023GXNSFAA026469)
National Natural Science Foundation of China(22165002)
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