Polymer Single Crystal: From Crystallization Strategy to Functionalized Application

Tianyu Wu; Haozhe Huang; Junhao Wang; Haoyang Luo; Jun Xu; Haimu Ye

doi:10.7536/PC230702

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Prog Chem ›› 2023, Vol. 35 ›› Issue (12) : 1727-1751. DOI: 10.7536/PC230702

Review

Polymer Single Crystal: From Crystallization Strategy to Functionalized Application

Tianyu Wu ¹^,^* ,
Haozhe Huang ¹ ,
Junhao Wang ¹ ,
Haoyang Luo ¹ ,
Jun Xu ² ,
Haimu Ye ¹

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Abstract

In the 100 years since the birth of modern polymer science, polymer chemistry, polymer physics and polymer processing have developed rapidly and formed a more complete body of discipline. As an important part of polymer physics, polymer crystallography focuses on the microscopic crystallization process and reveals the unique behavior of polymer chains. Polymer crystals can be divided into single crystals and polycrystals according to the number of nuclei in an independence structure. Among them, polymer single crystals have closely arranged molecular chains and exhibit perfect geometrical symmetry in macroscopic morphology, with excellent mechanical and optoelectronic properties. However, due to the complexity of molecular chain movement, the formation of polymer single crystals is still very difficult. For decades, a large number of scientists have devoted themselves to the study of polymer single crystals and obtained abundant results. In this paper, we focus on the history and progress of polymer single crystal research, and carefully discuss the crystallization strategies of polymer single crystals and their functionalization applications, hoping to provide effective help to relevant researchers.

Key words

polymer single crystal / crystallization strategy / functionalized application

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Tianyu Wu , Haozhe Huang , Junhao Wang , et al . Polymer Single Crystal: From Crystallization Strategy to Functionalized Application[J]. Progress in Chemistry. 2023, 35(12): 1727-1751 https://doi.org/10.7536/PC230702

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Funding

National Natural Science Foundation of China(52203030)

China University of Petroleum(Beijing)Research Fund(2462022BJRC008)

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