Performance Improvement Strategy of Photocatalytic Ammonia Synthesis Catalyst

Lijun Guo; Hong Yang; Shengjuan Shao; Yinqi Liu; Jianxin Liu

doi:10.7536/PC231202

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Prog Chem ›› 2024, Vol. 36 ›› Issue (6) : 939-948. DOI: 10.7536/PC231202

Review

Performance Improvement Strategy of Photocatalytic Ammonia Synthesis Catalyst

Lijun Guo ¹^,^* ,
Hong Yang ¹ ,
Shengjuan Shao ¹ ,
Yinqi Liu ¹ ,
Jianxin Liu ²^,^*

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Abstract

Photocatalytic nitrogen fixation is driven by solar energy.N₂and H₂O are used to directly produce NH₃at normal temperature and pressure,and the process has zero carbon emissions.It is one of the most promising artificial nitrogen fixation methods and has attracted wide attention from researchers in recent years.Limited by the difficult activation of N₂,low utilization rate of photogenerated carrier and low utilization rate of sunlight,the ammonia production efficiency is still not high,so improving the ammonia production efficiency is the focus of research in the field of photocatalytic ammonia synthesis.Starting from the three important processes of N₂adsorption activation,carrier separation and migration,and surface reaction,it is very promising to promote the activation and conversion of N₂under mild conditions and produce NH₃efficiently by reasonable modification of the catalyst.This paper mainly studied the modification of photocatalysts,summarized the influence of N₂molecular adsorption and activation ability,photogenerated electron transfer ability and light utilization on the ammonia production efficiency,analyzed the research in recent years in these fields,and finally summarized the modification strategy of photocatalytic ammonia synthesis catalyst.

Contents

1 Introduction

2 Improving the adsorption and activation capacity of N₂

2.1 Introducing defect site

2.2 Introducing metal site

3 Increased charge transfer capacity

3.1 Constructing the monometal mixed valence catalyst

3.2 Designing bimetallic site catalyst

3.3 Constructing multi-metal site catalyst

4 Improving light utilization

5 Conclusion and outlook

Key words

photocatalytic synthesis of ammonia / photocatalyst / active site / photogenic electron transfer ability / morphology control

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Lijun Guo , Hong Yang , Shengjuan Shao , et al . Performance Improvement Strategy of Photocatalytic Ammonia Synthesis Catalyst[J]. Progress in Chemistry. 2024, 36(6): 939-948 https://doi.org/10.7536/PC231202

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Funding

National Natural Science Foundation of China(21978187)

Fundamental Research Program of Shanxi Province(202203021221058)

Scientific Technological Innovation Programs of Higher Education Institutions in Shanxi(2022L535)

Taiyuan Institute of Technology Scientific Research Initial Funding(2024KJ013)

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