Multiple-Responsive Pickering Emulsion Interfacial Catalysis and Its Application

Mingxia Zhang; Heng Zhang; Anguo Ying

doi:10.7536/PC240720

PDF(5045 KB)

Prog Chem ›› 2025, Vol. 37 ›› Issue (7) : 1074-1090. DOI: 10.7536/PC240720

Review

Multiple-Responsive Pickering Emulsion Interfacial Catalysis and Its Application

Author information +

History +

Abstract

In recent years， Pickering emulsions have attracted substantial attention owing to their facile preparation and superior stability. Pickering emulsions are emulsions stabilized by solid particles that are far more stable than conventional emulsions. Solid particles， acting as the core part of the emulsion system， play an important role in the preparation and application of Pickering emulsions. Here， this review concentrates on the impact of various single stimulus responses （pH， temperature， carbon dioxide， redox， light irradiation， magnetic fields） and multiplexed stimulus responses on the stability and performance of Pickering emulsion systems. Additionally， it highlights the latest research and advancements concerning the application of Pickering emulsion systems in a multitude of reactions， such as oxidation reaction， reduction reaction， hydrolysis reaction， condensation reaction， esterification transesterification reaction， and cascade reaction.

Contents

1 Introduction

2 Responsive Pickering emulsion

2.1 pH-responsive

2.2 Temperature-responsive

2.3 CO₂-responsive

2.4 Ox/Red-responsive

2.5 Light-responsive

2.6 Magnetoresponsive

2.7 Multiresponsive

3 Application

3.1 Pickering emulsion in oxidation reactions

3.2 Pickering emulsion in reduction reactions

3.3 Pickering emulsion in hydrolysis reactions

3.4 Pickering emulsion in condensation reactions

3.5 Pickering emulsion in esterification transesterification reactions

3.6 Pickering emulsion in cascade reactions

4 Conclusion and outlook

Key words

Pickering emulsions / wettability / stimulus-responsiveness / interfacial catalysis / reactive application

Cite this article

EndNote

Ris (Procite)

Bibtex

Download Citations

Mingxia Zhang , Heng Zhang , Anguo Ying. Multiple-Responsive Pickering Emulsion Interfacial Catalysis and Its Application[J]. Progress in Chemistry. 2025, 37(7): 1074-1090 https://doi.org/10.7536/PC240720

References

List( Publishing order | Descend order by publishing year | Descend order by cited within ) Chart analysis

[1]	Binks B P. Curr. Opin. Colloid Interface Sci., 2002, 7(1/2): 21. Cited in this article [1]

[2]	Frelichowska J, Bolzinger M A, Pelletier J, Valour J P, Chevalier Y. Int. J. Pharm., 2009, 371(1/2): 56. Cited in this article [2]

[3]	Ramsden W. Proc. R. Soc. Lond., 1904, 72(477/486): 156. Cited in this article [1]

[4]	Pickering S U. J. Chem. Soc., Trans., 1907, 91: 2001. Cited in this article [1]

[5]	Binks B P, Lumsdon S O. Langmuir, 2000, 16(23): 8622. Cited in this article [1]

[6]	Binks B P, Lumsdon S O. Langmuir, 2001, 17(15): 4540. Cited in this article [1]

[7]	Tambe D E, Sharma M M. J. Colloid Interface Sci., 1993, 157(1): 244. Cited in this article [1]

[8]	Huang X M, Luo Z J, Guo J, Ruan Q J, Wang J M, Yang X Q. J. Agric. Food Chem., 2020, 68(33): 8890. Cited in this article [1]

[9]	Kaptay G. Colloids Surf. A Physicochem. Eng. Aspects, 2006, 282/283: 387. Cited in this article [1]

[10]	Tang J T, Quinlan P J, Tam K C. Soft Matter, 2015, 11(18): 3512. Cited in this article [1]

[11]	Manfredini N, Merigo M, Ilare J, Sponchioni M, Moscatelli D. Nanoscale, 2021, 13(18): 8543. Cited in this article [1]

[12]	Tavasoli S, Liu Q, Jafari S M. Food Hydrocoll., 2022, 124: 107280. Cited in this article [1]

[13]	Li Z, Yu D H. Ind. Crops Prod., 2023, 203: 117158. Cited in this article [1]

[14]	Chevalier Y, Bolzinger M A. Colloids Surf. A Physicochem. Eng. Aspects, 2013, 439: 23. Cited in this article [1]

[15]	Dai H, Li K R. J. Environ. Chem. Eng., 2023, 11(5): 110361. Cited in this article [1]

[16]	Li Z, Yu D H. Int. J. Biol. Macromol., 2023, 242: 124942. Cited in this article [1]

[17]	Zhang Q M, Zhao Q F, Zhu B B, Chen R, Zhou Y T, Pei X P, Zhou H, An H Y, Tan Y, Chen C S. Int. J. Biol. Macromol., 2023, 244: 125393. Cited in this article [1]

[18]	Shirjandi M, Haddadi-Asl V, Abdollahi E, Khanipour F. Polymer, 2022, 255: 125111. Cited in this article [1]

[19]	Zhang J Q, Li H C, Wang J, Liu S S, Li J, Li D Q. Colloids Surf. A Physicochem. Eng. Aspects, 2023, 673: 131807. Cited in this article [1]

[20]	Mao Q, Li M, Zhang S J, Zhang X J, He G H, Zhang W J. Int. J. Biol. Macromol., 2020, 162: 1888. Cited in this article [1]

[21]	Xin Y, Liu Z Z, Yang C H, Dong C, Chen F S, Liu K L. Int. J. Biol. Macromol., 2023, 253: 127064. Cited in this article [1]

[22]	Low L E, Tey B T, Ong B H, Chan E S, Tang S Y. Carbohydr. Polym., 2017, 155: 391. Cited in this article [1]

[23]	Shang X X, Liu Q, Qin T, Xu X D, Sun H M, Liu M X, Zhu H D. Int. J. Nanomed., 2019, 14: 3361. Cited in this article [1]

[24]	Saffarionpour S. Food Bioprocess Technol., 2020, 13(8): 1292. Cited in this article [1]

[25]	Acter S, Vidallon M L P, King J P, Teo B M, Tabor R F. J. Mater. Chem. B, 2021, 9(43): 8962. Cited in this article [1]

[26]	Gao K, Liu J Y, Li X, Gojzewski H, Sui X F, Vancso G J. ACS Sustainable Chem. Eng., 2022, 10(29): 9334. Cited in this article [1]

[27]	Wei S H, Liu B, Huang X N, Xi Y K, Wang S X, Wang L K, Yin S W, Yang X Q. ACS Sustainable Chem. Eng., 2023, 11(39): 14358. Cited in this article [1]

[28]	Zhang Z, Cheng M, Gabriel M S, Teixeira Neto Â A, da Silva Bernardes J, Berry R, Tam K C. J. Colloid Interface Sci., 2019, 555: 489. Cited in this article [1]

[29]	Maingret V, Courrégelongue C, Schmitt V, Héroguez V. Biomacromolecules, 2020, 21(12): 5358. Cited in this article [2]

[30]	Liu P, Wu J H, Pei X M, Cui Z G, Jiang J Z, Song B L, Binks B P. Green Chem., 2022, 24(19): 7612. Cited in this article [4]

[31]	Dechézelles J F, Feng Y Y, Fadil F, Nardello-Rataj V. Colloids Surf. A Physicochem. Eng. Aspects, 2021, 631: 127641. Cited in this article [4]

[32]	Chen A, Wang D, Chen J S, Xu J H, Zeng H B. Engineering, 2022, 12: 48. Cited in this article [2]

[33]	Guo S, Zhang Y M. Colloids Surf. A Physicochem. Eng. Aspects, 2019, 562: 119. Cited in this article [2]

[34]	Yu S J, Zhang H J, Jiang J Z, Cui Z G, Xia W S, Binks B P. Green Chem., 2020, 22(16): 5470. Cited in this article [4]

[35]	Zhao X Y, Fang X Q, Yang S J, Zhang S Q, Yu G B, Liu Y Y, Zhou Y, Feng Y H, Li J C. Carbohydr. Polym., 2021, 251: 117072. Cited in this article [2]

[36]	Zhou S J, Sheng K, Zhang N, Yuan S D, Feng N, Song Y X, Geng J F, Xin X. J. Mol. Liq., 2022, 367: 120384. Cited in this article [4]

[37]	Zou Y L, Zhang Y T, Liu X Y, Zhang H X. Catal. Lett., 2020, 150(12): 3608. Cited in this article [2]

[38]	He R N, Sun S Q, Cui J P, Chi M S, Wang Z K, Hu S Q. Phys. Chem. Chem. Phys., 2023, 25(37): 25780. Cited in this article [7]

[39]	Douyère G, Leclercq L, Nardello-Rataj V. Colloids Surf. A Physicochem. Eng. Aspects, 2021, 631: 127705. Cited in this article [2]

[40]	Zhang L, Zhang G C, Ge J J, Jiang P, Ding L. J. Colloid Interface Sci., 2022, 616: 129. Cited in this article [2]

[41]	Zhang M, Ma X L, Yang W G, Wang F, Yu H, Song A X. J. Mol. Liq., 2021, 341: 116906. Cited in this article [5]

[42]	Zhang Z Y, Li Q H, Ge S J, Li X S, Zhang Z L, Zhao W L. Nano, 2022, 17(06): 2250043. Cited in this article [2]

[43]	Jia K L, Guo Y S, Yu Y, Zhang J J, Yu L F, Wen W, Mai Y L. Soft Matter, 2021, 17(12): 3346. Cited in this article [2]

[44]	Shan Y Y, Yu C, Zhang M D, Wei Q B, An J L, Lv H H, Ni L, Qiu J S. ChemSusChem, 2022, 15(7): e202102473. Cited in this article [3]

[45]	Lu S, Yang D J, Wang M, Yan M Z, Qian Y, Zheng D F, Qiu X Q. Colloids Surf. A Physicochem. Eng. Aspects, 2020, 585: 124158. Cited in this article [4]

[46]	Geng J M, Pu J Y, Zhao Y, Lin B H, Bai B J, Thomas S P. Fuel, 2019, 258: 116159. Cited in this article [2]

[47]	Ahmed R, Wang M W, Qi Z Y, Hira N U A, Jiang J H, Zhang H S, Iqbal S, Wang J Y, Stuart M A C, Guo X H. ACS Omega, 2021, 6(28): 17915. Cited in this article [3]

[48]	Dupin D, Armes S P, Connan C, Reeve P, Baxter S M. Langmuir, 2007, 23(13): 6903. Cited in this article [1]

[49]	Fujii S, Cai Y L, Weaver J V M, Armes S P. J. Am. Chem. Soc., 2005, 127(20): 7304. Cited in this article [1]

[50]	Xi Y K, Liu B, Jiang H, Yin S W, Ngai T, Yang X Q. Chem. Sci., 2020, 11(15): 3797. Cited in this article [1]

[51]	Cai X R, Wang Y, Du X F, Xing X Y, Zhu G L. Food Hydrocoll., 2020, 109: 106093. Cited in this article [1]

[52]	Liu L, Pu X L, Zhou Y, Zhou J, Luo D, Ren Z F. Colloids Surf. A Physicochem. Eng. Aspects, 2020, 586: 124246. Cited in this article [1]

[53]	Xie Y Q, Xu Y, Xu J. J. Colloid Interface Sci., 2021, 597: 383. Cited in this article [1]

[54]	Yu S J, Lv M, Lu G P, Cai C, Jiang J Z, Cui Z G. Langmuir, 2021, 37(36): 10683. Cited in this article [1]

[55]	Tang C M, Chai Y Y, Wang C X, Wang Z X, Min J W, Wang Y F, Qi W, Su R X, He Z M. Langmuir, 2022, 38(42): 12849. Cited in this article [1]

[56]	Siebenmorgen C, Zu G Y, Keskin D, van Rijn P. Macromol. Rapid Commun., 2022, 43(15): 2100766. Cited in this article [1]

[57]	Xue W, Yang H Q, Du Z P. Langmuir, 2017, 33(39): 10283. Cited in this article [1]

[58]	Li K R, Dai H, Li J, Zhang Q, Wang B. Colloids Surf. A Physicochem. Eng. Aspects, 2022, 648: 129281. Cited in this article [1]

[59]	Xiao Z G, Wang L S, Lv C Y, Guo S L, Lu X X, Tao L W, Duan Q S, Yang Q Y, Luo Z G. Int. J. Biol. Macromol., 2020, 143: 401. Cited in this article [2]

[60]	Jiang H, Zhang S W, Sun G Q, Li Y X, Guan X, Yang C, Ngai T. Chem. Sci., 2022, 13(1): 39. Cited in this article [1]

[61]	Månsson L K, Peng F F, Crassous J J, Schurtenberger P. Soft Matter, 2020, 16(7): 1908. Cited in this article [1]

[62]	Li X X, Wang Y Y, Hou Q F, Cai W F, Xu Y, Zhao Y J. Res. Chem. Intermed., 2021, 47(9): 3899. Cited in this article [1]

[63]	Merland T, Waldmann L, Guignard O, Tatry M C, Wirotius A L, Lapeyre V, Garrigue P, Nicolai T, Benyahia L, Ravaine V. J. Colloid Interface Sci., 2022, 608: 1191. Cited in this article [1]

[64]	Tatry M C, Galanopoulo P, Waldmann L, Lapeyre V, Garrigue P, Schmitt V, Ravaine V. J. Colloid Interface Sci., 2021, 589: 96. Cited in this article [1]

[65]	Wen R, Fu S Y. J. Wood Chem. Technol., 2022, 42(6): 456. Cited in this article [1]

[66]	Wang Y, Wang H B, Li C L, Sun S Q, Hu S Q. J. Ind. Eng. Chem., 2021, 97: 492. Cited in this article [1]

[67]	Li H X, Liu Y S, Jiang J Z. Green Chem., 2022, 24(20): 8062. Cited in this article [3]

[68]	Pei X M, Wu J H, Zou X Y, Song B L, Chen Z, Liu P, Cui Z G, Pan T, Gu Y. J. Mol. Liq., 2022, 363: 119915. Cited in this article [3]

[69]	Richards K D, Evans R C. Soft Matter, 2022, 18(31): 5770. Cited in this article [1]

[70]	Sun N, Li Q H, Zhang Z Y, Ge S J, Chang X J, Yu M C, Li A X, Ma Y F. Colloids Surf. A Physicochem. Eng. Aspects, 2021, 619: 126494. Cited in this article [3]

[71]	Zhong H Y, Zhang Y, Gong Y M, Wan C Y, Zhang Y F, Zheng M M. ACS Sustainable Chem. Eng., 2024, 12(5): 1857. Cited in this article [3]

[72]	Lu X T, Li S N, Wang L M, Huang S J, Liu Z Q, Liu Y J, Ying A G. Fuel, 2022, 310: 122318. Cited in this article [2]

[73]	Yang S J, Qin W Q, Zhao X Y, He F R, Gong H K, Liu Y Y, Feng Y H, Zhou Y, Yu G B, Li J C. Carbohydr. Polym., 2021, 266: 118121. Cited in this article [1]

[74]	Li X J, Zhu P Y, Lv X, Yan G J, Lu H S. Langmuir, 2020, 36(47): 14288. Cited in this article [3]

[75]	Tang J, Zhou X, Cao S X, Zhu L Y, Xi L L, Wang J L. ACS Appl. Mater. Interfaces, 2019, 11(17): 16156. Cited in this article [3]

[76]	Qi L, Luo Z G, Lu X X. Green Chem., 2018, 20(7): 1538. Cited in this article [3]

[77]	Li Z Y, Shi Y L, Zhu A L, Zhao Y L, Wang H Y, Binks B P, Wang J J. Angew. Chem. Int. Ed., 2021, 60(8): 3928. Cited in this article [1]

[78]	Ma S H, Zong W, Han X J. New J. Chem., 2021, 45(8): 3974. Cited in this article [3]

[79]	Zhang T T, Jiang H, Hong L Z, Ngai T. Chem. Sci., 2022, 13(36): 10752. Cited in this article [1]

[80]	Luo R D, Dong J F, Luo Y B. RSC Adv., 2020, 10(69): 42423. Cited in this article [3]

[81]	Wang C, Chi H, Zhang F, Wang X Y, Wang J R, Zhang H, Liu Y, Huang X N, Bai Y G, Xu K, Wang P X. Chem. Sci., 2022, 13(30): 8766. Cited in this article [3]

[82]	Jiang W L, Fu Q J, Yao B J, Ding L G, Liu C X, Dong Y B. ACS Appl. Mater. Interfaces, 2017, 9(41): 36438. Cited in this article [3]

[83]	Shi Y L, Xiong D Z, Li Z Y, Wang H Y, Qiu J K, Zhang H C, Wang J J. ACS Appl. Mater. Interfaces, 2020, 12(47): 53385. Cited in this article [3]

[84]	Qi L, Zhou Y J, Luo Z G, Gao Q Y, Shi Y C. Carbohydr. Polym., 2023, 299: 120203. Cited in this article [3]

[85]	Li S N, Lu X T, Liu Q, Wang L M, Liu Y J, Liu Z Q, Ying A G. J. Mater. Chem. A, 2022, 10(7): 3531. Cited in this article [1]

[86]	Yang T, Zhang Y F, Xu L J, Zhu H, Zhang J T, Guo Z, Huang F H, Zheng M M. ACS Sustainable Chem. Eng., 2022, 10(21): 6963. Cited in this article [3]

[87]	Yang T, Zhang Y F, Wang J, Huang F H, Zheng M M. ACS Sustainable Chem. Eng., 2021, 9(36): 12070. Cited in this article [5]

[88]	Rajoo A, Siva S P, Sia C S, Chan E S, Tey B T, Low L E. European Journal of Pharmaceutics and Biopharmaceutics, 2024, 205: 114572. Cited in this article [1]

[89]	Guzmán E. ChemCatChem, 2024, 16(20): e202400856. Cited in this article [1]

[90]	Chen Q L, Ye T., Yang, S J, Fan L W, Shang C N, Feng Y H, Li J C, Wang Y J, Yu G B, Dai J. International Journal of Biological Macromolecules, 2025, 310: 142721. Cited in this article [1]