Circularly Polarized Organic Room Temperature Phosphorescent Materials

Hengyu Cao; Zhisheng Gao; Xin Yan; Huanhuan Li; Ye Tao

doi:10.7536/PC240907

PDF(10834 KB)

Prog Chem ›› 2025, Vol. 37 ›› Issue (7) : 949-966. DOI: 10.7536/PC240907

Review

Circularly Polarized Organic Room Temperature Phosphorescent Materials

Author information +

History +

Abstract

In recent years， a series of organic room temperature phosphorescence materials with circular polarization luminescence have been constructed by combining （circularly polarized room temperature phosphorescence， CPRTP）materials with reasonable molecular design. The luminescence principle of CPRTP materials is consistent with the luminescence of organic room-temperature phosphorescence materials， and is accompanied by the property of circularly polarized luminescence. This kind of material not only retains the advantage of low energy loss in circular polarization luminescence， but also greatly expands the application of organic room-temperature phosphorescence materials in the fields of anti-counterfeiting encryption and afterglow display. In this paper based on the luminescence mechanism and molecular strategy of CPRTP materials， the structural design strategy of CPRTP materials is summarized. Finally， the existing problems of CPRTP materials are discussed， and the future development prospects and challenges are prospected.

Contents

1 Introduction

2 Molecular designs of CPRTP materials and their applications

2.1 Host-gust CPRTP materials

2.2 Organic small molecular CPRTP materials

2.3 Organic ionic crystals CPRTP materials

2.4 Organic polymers CPRTP materials

2.5 Supramolecular self-assembly CPRTP materials

3 Summary and outlook

Key words

circularly polarized luminescence / room temperature phosphorescence / chiral / molecular designs

Cite this article

EndNote

Ris (Procite)

Bibtex

Download Citations

Hengyu Cao , Zhisheng Gao , Xin Yan , et al . Circularly Polarized Organic Room Temperature Phosphorescent Materials[J]. Progress in Chemistry. 2025, 37(7): 949-966 https://doi.org/10.7536/PC240907

References

List( Publishing order | Descend order by publishing year | Descend order by cited within ) Chart analysis

[1]	Zhao W J, He Z K, Tang B Z. Nat. Rev. Mater., 2020, 5(12): 869. Cited in this article [1]

[2]	Guo J J, Yang C L, Zhao Y L. Acc. Chem. Res., 2022, 55(8): 1160. Cited in this article [1]

[3]	Shi H F, Yao W, Ye W P, Ma H L, Huang W, An Z F. Acc. Chem. Res., 2022, 55(23): 3445. Cited in this article [1]

[4]	Xu S, Chen R F, Zheng C, Huang W. Adv. Mater., 2016, 28(45): 9920. Cited in this article [1]

[5]	Peng Q, Ma H L, Shuai Z G. Acc. Chem. Res., 2021, 54(4): 940. Cited in this article [1]

[6]	Nie H G, Wei Z, Ni X L, Liu Y. Chem. Rev., 2022, 122(9): 9032. Cited in this article [1]

[7]	Yang X, Waterhouse G I N, Lu S Y, Yu J H. Chem. Soc. Rev., 2023, 52(22): 8005. Cited in this article [1]

[8]	Li Q Q, Li Z. Adv. Sci., 2017, 4(7): 1600484. Cited in this article [5]

[9]	An Z F, Zheng C, Tao Y, Chen R F, Shi H F, Chen T, Wang Z X, Li H H, Deng R R, Liu X G, Huang W. Nat. Mater., 2015, 14(7): 685. Cited in this article [1]

[10]	Tao Y, Chen R F, Li H H, Yuan J, Wan Y F, Jiang H, Chen C L, Si Y B, Zheng C, Yang B C, Xing G C, Huang W. Adv. Mater., 2018, 30(44): 1803856. Cited in this article [1]

[11]	Singh M, Shen K, Ye W P, Gao Y H, Lv A Q, Liu K, Ma H L, Meng Z G, Shi H F, An Z F. Angew. Chem. Int. Ed., 2024, 63(14): e202319694. Cited in this article [1]

[12]	Cong Z X, Han M M, Fan Y Y, Fan Y H, Chang K, Xiao L Y, Zhang Y F, Zhen X, Li Q Q, Li Z. Mater. Chem. Front., 2022, 6(12): 1606. Cited in this article [1]

[13]	Yan X, Peng H, Xiang Y, Wang J, Yu L, Tao Y, Li H H, Huang W, Chen R F. Small, 2022, 18(1): 2104073. Cited in this article [1]

[14]	Dou X Y, Wang X, Xie X L, Zhang J, Li Y, Tang B. Adv. Funct. Mater., 2024, 34(23): 2314069. Cited in this article [1]

[15]	Gong Z K, Xu H. Prog. Chem., 2023, 34(11): 2432. Cited in this article [1]

[16]	Xu X, Yan B. Phys. Chem. Chem. Phys., 2023, 25(3): 1457. Cited in this article [1]

[17]	Wang H, Shi H F, Ye W P, Yao X K, Wang Q, Dong C M, Jia W Y, Ma H L, Cai S Z, Huang K W, Fu L S, Zhang Y Y, Zhi J H, Gu L, Zhao Y L, An Z F, Huang W. Angew. Chem. Int. Ed., 2019, 58(52): 18776. Cited in this article [1]

[18]	Zhou B, Yan D P. Adv. Funct. Mater., 2019, 29(4): 1807599. Cited in this article [1]

[19]	Zheng H, Zhang Z Y, Cai S Z, An Z F, Huang W. Adv. Mater., 2024, 36(18): 2311922. Cited in this article [1]

[20]	Gan N, Shi H F, An Z F, Huang W. Adv. Funct. Mater., 2018, 28(51): 1802657. Cited in this article [1]

[21]	Zhang Y Q, Chen L, Liu B, Yu S P, Yang Y Z, Liu X G. Adv. Funct. Mater., 2024, 34(25): 2315366. Cited in this article [1]

[22]	Liao Q Y, Li Q Q, Li Z. Adv. Mater., 2023, DOI: 10.1002/adma.202306617. Cited in this article [1]

[23]	Mei J, Hong Y N, Lam J W Y, Qin A J, Tang Y H, Tang B Z. Adv. Mater., 2014, 26(31): 5429. Cited in this article [1]

[24]	Sun Y Q, Zhang X J, Zhuang J L, Zhang H R, Hu C F, Zheng M T, Lei B F, Liu Y L. Carbon, 2020, 165: 306. Cited in this article [1]

[25]	Zhou Q, Yang C L, Zhao Y L. Chem, 2023, 9(9): 2446. Cited in this article [1]

[26]	Luo X F, He J, Wang Y, Dai H, Wu Z G. Chin. J. Struct. Chem., 2023, 41(12): 2212070. Cited in this article [1]

[27]	Han J M, Guo S, Lu H, Liu S J, Zhao Q, Huang W. Adv. Opt. Mater., 2018, 6(17): 1800538. Cited in this article [1]

[28]	Wang Q, Liu Y Q, Wu Z Q. Chin. J. Org. Chem., 2023, 43(12): 4141 (王倩, 刘雨奇, 吴宗铨. 有机化学, 2023, 43(12): 4141). Cited in this article [1]

[29]	Zhou L, Chen K, Zhou X Y, Wu Z Q. Chem. Res. Chin. Univ., 2023, 39(5): 719. Cited in this article [1]

[30]	Yu L, Xue P R, Li H H, Tao Y, Chen R F, Huang W. Prog. Chem., 2022, 34(9): 1996 (于兰, 薛沛然, 李欢欢, 陶冶, 陈润锋, 黄维. 化学进展, 2022, 34(9):1996). Cited in this article [1]

[31]	Gong Z L, Zhu X F, Zhou Z H, Zhang S W, Yang D, Zhao B, Zhang Y P, Deng J P, Cheng Y X, Zheng Y X, Zang S Q, Kuang H, Duan P F, Yuan M J, Chen C F, Zhao Y S, Zhong Y W, Tang B Z, Liu M H. Sci. China Chem., 2021, 64(12): 2060. Cited in this article [1]

[32]	Yu J X, Duan B H, Chen Z, Liu N, Wu Z Q. ChemPlusChem, 2024, 89(5): e202300481. Cited in this article [1]

[33]	Patil Y, Demangeat C, Favereau L. Chirality, 2023, 35(7): 390. Cited in this article [1]

[34]	Liu D, Wang W J, Alam P, Yang Z, Wu K W, Zhu L X, Xiong Y, Chang S, Liu Y, Wu B, Wu Q, Qiu Z J, Zhao Z, Tang B Z. Nat. Photonics., 2024, 18(12):1276. Cited in this article [1]

[35]	Yang S Y, Qu Y K, Liao L S, Jiang Z Q, Lee S T. Adv. Mater., 2022, 34(22): 2104125. Cited in this article [1]

[36]	Hirata S, Vacha M. J. Phys. Chem. Lett., 2016, 7(8): 1539. Cited in this article [3]

[37]	Wang L, Hao A Y, Xing P Y. ACS Appl. Mater. Interfaces, 2022, 14(39): 44902. Cited in this article [3]

[38]	Xu M C, Wu X Y, Yang Y, Ma C H, Li W, Yu H P, Chen Z J, Li J, Zhang K, Liu S X. ACS Nano, 2020, 14(9): 11130. Cited in this article [3]

[39]	Huang W B, Fu C Y, Liang Z W, Zhou K, He Z K. Angew. Chem. Int. Ed., 2022, 61(30): e202202977. Cited in this article [3]

[40]	Garain S, Sarkar S, Chandra Garain B, Pati S K, George S J. Angew. Chem. Int. Ed., 2022, 61(11): e202115773. Cited in this article [3]

[41]	Xu C, Yin C J, Wu W J, Ma X. Sci. China Chem., 2022, 65(1): 75. Cited in this article [3]

[42]	Chen B, Huang W H, Zhang G Q. Nat. Commun., 2023, 14: 1514. Cited in this article [3]

[43]	Jiang Y T, Zhang C Y, Wang R X, Lei Y X, Dai W B, Liu M C, Wu H Y, Tao Y, Huang X B. Adv. Opt. Mater., 2024, 12(13): 2302482. Cited in this article [1]

[44]	Ma C Q, Ma H L, Ling K, Zheng R L, Gu M X, Song L L, An Z F, Shi H F, Huang W. J. Mater. Chem. C, 2018, 6(38): 10179. Cited in this article [3]

[45]	Li H, Li H H, Wang W, Tao Y, Wang S, Yang Q Q, Jiang Y B, Zheng C, Huang W, Chen R F. Angew. Chem. Int. Ed., 2020, 59(12): 4756. Cited in this article [3]

[46]	Li J N, Song Z C, Chen Y T, Xu C, Li S F, Peng Q E, Shi G, Liu C, Luo S L, Sun F Q, Zhao Z J, Chi Z G, Zhang Y, Xu B J. Chem. Eng. J., 2021, 418: 129167. Cited in this article [3]

[47]	Liang X, Liu T T, Yan Z P, Zhou Y, Su J, Luo X F, Wu Z G, Wang Y, Zheng Y X, Zuo J L. Angew. Chem. Int. Ed., 2019, 58(48): 17220. Cited in this article [3]

[48]	Li H, Gu J, Wang Z, Wang J, He F, Li P, Tao Y, Li H, Xie G, Huang W, Zheng C, Chen R. Nat. Commun., 2022, 13(1):429. Cited in this article [3]

[49]	Yu L, Gao Z S, Cheng H, Yan X, Cao H Y, Guo G Y, Li H H, Li P, Chen R F, Tao Y. Small, 2023, 19(46): 2303579. Cited in this article [1]

[50]	Chen W J, Tian Z M, Li Y G, Jiang Y Q, Liu M H, Duan P F. Chem., 2018, 24(66): 17444. Cited in this article [3]

[51]	Gu L, Ye W P, Liang X, Lv A Q, Ma H L, Singh M, Jia W Y, Shen Z C, Guo Y, Gao Y R, Chen H Z, Wang D D, Wu Y L, Liu J W, Wang H, Zheng Y X, An Z F, Huang W, Zhao Y L. J. Am. Chem. Soc., 2021, 143(44): 18527. Cited in this article [3]

[52]	Liu R H, Ding B B, Liu D Z, Ma X. Chem. Eng. J., 2021, 421: 129732. Cited in this article [3]

[53]	Huang Z Z, He Z Y, Ding B B, Tian H, Ma X. Nat. Commun., 2022, 13: 7841. Cited in this article [3]

[54]	Zhang D W, Li M, Chen C F. Angew. Chem. Int. Ed., 2022, 61(47): e202213130. Cited in this article [1]

[55]	Xu M C, Xu Z, Soto M A, Xu Y T, Hamad W Y, MacLachlan M J. Adv. Mater., 2023, 35(29): 2301060. Cited in this article [3]

[56]	Xu L, Wu Y J, Gao R T, Li S Y, Liu N, Wu Z Q. Angew. Chem. Int. Ed., 2023, 62(13): e202217234. Cited in this article [3]

[57]	Zhang C Y, Yan X, Gao Z S, Cheng H, Zhang X, Li H H, Chen R F, Li H, Xie G Z, Tao Y. Chem. Eng. J., 2024, 485: 149886. Cited in this article [3]

[58]	Zeng M J, Wang W G, Zhang S M, Gao Z S, Yan Y M, Liu Y T, Qi Y L, Yan X, Zhao W, Zhang X, Guo N N, Li H H, Li H, Xie G Z, Tao Y, Chen R F, Huang W. Nat. Commun., 2024, 15: 3053. Cited in this article [3]

[59]	Liu J, Song Z P, Wei J, Wu J J, Wang M Z, Li J G, Ma Y, Li B X, Lu Y Q, Zhao Q. Adv. Mater., 2024, 36(7): 2306834. Cited in this article [1]

[60]	Huang A, Huang J, Luo H Y, Luo Z W, Wang P, Wang P, Guan Y, Xie H L. J. Mater. Chem. C, 2023, 11(12): 4104. Cited in this article [1]

[61]	Wang X J, Yang K, Zhao B, Deng J P. Small, 2024, 20(43): 2404576. Cited in this article [1]

[62]	Liu C, Li H, Chen Y H, Xu D, Cheng Y X. Chem. Eng. J., 2024, 486: 150442. Cited in this article [3]

[63]	Xu D, Liu C, Li H, Cheng Y X, Zheng W H. Adv. Opt. Mater., 2024, 12(15): 2303019. Cited in this article [3]

[64]	Liu J, Wu J J, Wei J, Huang Z J, Zhou X Y, Bao J Y, Lan R C, Ma Y, Li B X, Yang H, Lu Y Q, Zhao Q. Angew. Chem. Int. Ed., 2024, 63(12): e202319536. Cited in this article [3]

[65]	Cao M N, Ren Y R, Wu Y, Shen J J, Li S J, Yu Z Q, Liu S X, Li J, Rojas O J, Chen Z J. Nat. Commun., 2024, 15: 2375. Cited in this article [3]