Graphene Flexible Electrothermal Materials
Received date: 2024-05-03
Revised date: 2024-11-17
Online published: 2025-02-10
Supported by
National Natural Science Foundation of China(52372020)
Graphene is a two-dimensional nanomaterial with ultra-high thermal conductivity, which is widely used in the field of electric heating. By analyzing the research progress of graphene and its flexible electrothermal (membrane) materials, the preparation methods of graphene of different sizes and the effect of functional modification on the thermal conductivity of graphene are introduced. The applications of graphene flexible electric heating (film) materials in the fields of deicing and anti-fogging, wearable clothing and low-temperature battery thermal management are summarized. In the future, it is still necessary to break through the technical problems of the preparation process of graphene and its flexible heating (film) materials and the integration of heating elements.
1 Introduction
2 Preparation and modification of graphene materials
2.1 Small flake graphene
2.2 Large flake graphene
2.3 Functionalization of graphene
3 Graphene electrothermal composite materials
3.1 Graphene resin based materials
3.2 Graphene electrothermal film materials
4 Application of graphene electrothermal film
4.1 Defrosting and anti-fog
4.2 Wearable heating suit
4.3 Battery thermal management
4.4 Smart actuator
5 Conclusion and outlook
Yangyang Cai , Lixia Wei , Yizhou Zhu , Lei Lu , Xiao Liu . Graphene Flexible Electrothermal Materials[J]. Progress in Chemistry, 2025 , 37(3) : 455 -466 . DOI: 10.7536/PC240515
图2 Transformation Processes of Graphene and Other Carbon Materials[29] Note: 3D: Graphite; 2D: Graphene; 1D: Carbon Nanotubes; 0D: Fullerene BallsFig.2 Transformation process of graphene and other carbon material[29].Note: 3D, graphene; 2D, Graphene; 1D, carbon nanotubes; 0D, fullerene spheres. Copyright © 2007, Springer Nature |
图7 Application Scope of Composite Films: (a) Glass Vials, (b) Plastic Syringes, (c) PI Films, (d) Composite Films with Attachable Heating Performance, (e) Latex Gloves (After Folding), (f) Latex Gloves (Before Folding)[110]Fig.7 Application scope of composite film: (a) glass vial, (b) lastic syringe, (c) PI film, (d) composite film adhesive heating performance, (e) folded Latex Glove, (f) unfolded latex gloves[110]. Copyright © 2021, John Wiley and Sons |
图8 Solutions for Electric Vehicle Batteries[120]: A) Thermal Runaway of Batteries During Electric Vehicle Charging; B) Battery Pack Without a Battery Thermal Management System; C) Battery Pack With EG/PCM Material but Without Graphene Coating; D) EG/PCM/Graphene Composite for Passive Battery Thermal Management SystemsFig.8 Electric vehicle battery challenges and proposed solution[120]:A) Photographs showing TR-induced fires on charging electric vehicles; B) Battery without battery thermal management systems; C) Passive battery thermal management systems; D) Schematics of the EG/PCM/graphene composite for passive BTMS thermal management. Copyright © 2024, John Wiley and Sons |
[1] |
|
[2] |
|
[3] |
|
[4] |
|
[5] |
|
[6] |
|
[7] |
|
[8] |
|
[9] |
|
[10] |
|
[11] |
|
[12] |
|
[13] |
|
[14] |
|
[15] |
|
[16] |
|
[17] |
|
[18] |
|
[19] |
|
[20] |
|
[21] |
|
[22] |
|
[23] |
|
[24] |
|
[25] |
|
[26] |
|
[27] |
|
[28] |
|
[29] |
|
[30] |
(何新民, 张婷, 陈飞, 蒋俊. 化学进展, 2018, 30(4): 439.).
|
[31] |
|
[32] |
|
[33] |
|
[34] |
|
[35] |
|
[36] |
|
[37] |
|
[38] |
|
[39] |
|
[40] |
|
[41] |
|
[42] |
|
[43] |
|
[44] |
|
[45] |
|
[46] |
|
[47] |
|
[48] |
|
[49] |
|
[50] |
|
[51] |
|
[52] |
|
[53] |
|
[54] |
|
[55] |
|
[56] |
|
[57] |
|
[58] |
|
[59] |
|
[60] |
|
[61] |
|
[62] |
|
[63] |
|
[64] |
|
[65] |
|
[66] |
|
[67] |
|
[68] |
(陈宇, 张代军, 李军, 温嘉轩, 陈祥宝. 材料工程, 2021, 49(5): 82.).
|
[69] |
|
[70] |
|
[71] |
|
[72] |
|
[73] |
|
[74] |
|
[75] |
|
[76] |
(周醒, 胡斌, 肖文强, 姜豪, 张莉君, 王正君, 蔺海兰, 卞军, 赵新为. 材料研究学报, 2017, 31(11): 874.).
|
[77] |
|
[78] |
|
[79] |
|
[80] |
|
[81] |
|
[82] |
|
[83] |
|
[84] |
|
[85] |
|
[86] |
|
[87] |
|
[88] |
|
[89] |
|
[90] |
(宋雨晴. 中国科学技术大学博士论文, 2019.
|
[91] |
|
[92] |
|
[93] |
|
[94] |
|
[95] |
(王萍萍, 袁雪, 陈松, 刘书奇, 刘海洲, 刘岚. 功能材料, 2018, 49(2): 2214.).
|
[96] |
|
[97] |
|
[98] |
|
[99] |
|
[100] |
|
[101] |
|
[102] |
|
[103] |
|
[104] |
|
[105] |
(钱梦霜. 南京航空航天大学硕士论文, 2018.).
|
[106] |
|
[107] |
|
[108] |
|
[109] |
|
[110] |
|
[111] |
|
[112] |
|
[113] |
|
[114] |
|
[115] |
|
[116] |
|
[117] |
|
[118] |
|
[119] |
(刘阳坤. 哈尔滨工业大学硕士论文, 2019.).
|
[120] |
|
[121] |
|
[122] |
|
[123] |
|
[124] |
|
[125] |
|
[126] |
|
[127] |
|
[128] |
|
[129] |
|
[130] |
|
/
〈 |
|
〉 |