随着全球气候变化和人口数量的增长，人们对于植物生产的可持续发展需求更为迫切。纳米技术是21世纪发展最快的前沿科技之一，为促进农业可持续发展最有前景的工具之一。近年来，纳米材料调控植物生长的研究迅速发展，证实了其在传统植物生产中的潜在能力。为明确纳米材料对植物的促生作用及作用机制，本研究就纳米材料的吸收运输、纳米肥料、纳米植物生长调节剂、纳米酶与植物抗逆、纳米材料与光合作用等方面进行了论述，并指出纳米材料在植物生产领域面临的挑战和未来研究重点，强调要系统考虑纳米材料在农业生产中的应用，以期为后续纳米粒子调控植物生产的研究工作理清思路。

This research presents the mechanical creation of smart fertilizers from a mixture of smectite and urea in a 3:2 ratio by using the planetary milling technique. The smectite–urea composites show intercalation between urea and mineral, which increases steadily with increasing activation time. A shift of X-Ray Diffraction basal reflections, intensities of Fourier transform infrared spectroscopy (FTIR) peaks, and weight losses in thermogravimetric analysis (TG) document the systematic crystallo-chemical changes of the composites related to nitrogen interaction with activation. Observations of the nanocomposites by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) corroborate the inference. Nitrogen intercalates with smectite in the interlayer space and remains absorbed either within micro-aggregates or on the surface of activated smectites. Soil leaching tests reveal a slower rate of nitrogen than that of traditional urea fertilizers. Different forms of nitrogen within the composites cause their differential release rates to the soil. The formulated nanocomposite fertilizer enhances the quality and quantity of oat yield.

Lupin is an Andean legume that has gained importance in Ecuador due to the protein content in its grain. Nonetheless, in recent times the production of lupin has been affected by inadequate nutritional management. In order to avoid such circumstances, the current study spectrally analyzed lupin cultivation under the application of nanofertilizers and Fe and Zn chelates, within two controlled trials, using a radiometer spectrum, an active crop sensor and a multispectral sensor mounted on a UAV. Vegetation indices were generated and subsequently statistically analyzed using ANOVA and Tukey tests. In the field trial, the treatments lacked an indication of significant improvements, while in the greenhouse trial, the nanofertilizer treatments indicated better results compared to the control treatments. However, it was also determined that the application of nanofertilizers at a concentration of 540 ppm demonstrated significant efficiency in greenhouse conditions, which could not be achieved in the field. Furthermore, the chelate treatment presented a certain degree of toxicity for the plant.

Manganese (Mn) is an essential element for plants which intervenes mainly in photosynthesis. In this study we establish that manganese nanoparticles (MnNP) work as a better micronutrient than commercially available manganese salt, MnSO4 (MS) at recommended doses on leguminous plant mung bean (Vigna radiata) under laboratory condition. At higher doses it does not impart toxicity to the plant unlike MS. MnNP-treated chloroplasts show greater photophosphorylation, oxygen evolution with respect to control and MS-treated chloroplasts as determined by biophysical and biochemical techniques. Water splitting by an oxygen evolving complex is enhanced by MnNP in isolated chloroplast as confirmed by polarographic and spectroscopic techniques. Enhanced activity of the CP43 protein of a photosystem II (PS II) Mn4Ca complex influenced better phosphorylation in the electron transport chain in the case of MnNP-treated chloroplast, which is evaluated by sodium dodecyl sulfate polyacrylamide gel electrophoresis and corresponding Western blot analysis. To the best of our knowledge this is the first report to augment photosynthesis using MnNP and its detailed correlation with different molecular, biochemical and biophysical parameters of photosynthetic pathways. At effective dosage, MnNP is found to be biosafe both in plant and animal model systems. Therefore MnNP would be a novel potential nanomodulator of photochemistry in the agricultural sector.

The increasing severity of salinity stress, exacerbated by climate change, poses significant challenges to sustainable agriculture, particularly in salt-affected regions. Soil salinity, impacting approximately 20% of irrigated lands, severely reduces crop productivity by disrupting plants’ physiological and biochemical processes. This study evaluates the effectiveness of zinc (Zn) and silicon (Si) nanofertilizers in improving maize (Zea mays L.) growth, nutrient uptake, and yield under both saline and non-saline field conditions. ZnO nanoparticles (NPs) were synthesized via the co-precipitation method due to its ability to produce highly pure and uniform particles, while the sol–gel method was chosen for SiO2 NPs to ensure precise control over the particle size and enhanced surface activity. The NPs were characterized using UV-Vis spectroscopy, XRD, SEM, and TEM-EDX, confirming their crystalline nature, morphology, and nanoscale size (ZnO~12 nm, SiO2~15 nm). A split-plot field experiment was conducted to assess the effects of the nano and conventional Zn and Si fertilizers. Zn was applied at 10 ppm (22.5 kg/ha) and Si at 90 ppm (201 kg/ha). Various agronomic, chemical, and physiological parameters were then evaluated. The results demonstrated that nano Zn/Si significantly enhanced the cob length and grain yield. Nano Si led to the highest biomass increase (110%) and improved the nutrient use efficiency by 105% under saline and 110% under non-saline conditions compared to the control. Under saline stress, nano Zn/Si improved the nutrient uptake efficiency, reduced sodium accumulation, and increased the grain yield by 66% and 106%, respectively, compared to the control. A Principal Component Analysis (PCA) highlighted a strong correlation between nano Zn/Si applications with the harvest index and Si contents in shoots, along with other physiological and yield attributes. These findings highlight that nanotechnology-based fertilizers can mitigate salinity stress and enhance crop productivity, providing a promising strategy for sustainable agriculture in salt-affected soils.

Phosphorus (P) is a limiting factor to plant growth and productivity in almost half of the world's arable soil, and its uptake in plants is often constrained because of its low solubility in the soil. To avoid repeated and large quantity application of rock phosphate as a P fertilizer and enhance the availability of native P acquisition by the plant root surface, in this study a biosynthesized ZnO nanoparticle was used. Zn acts as a cofactor for P-solubilizing enzymes such as phosphatase and phytase, and nano ZnO increased their activity between 84 and 108%. The level of resultant P uptake in mung bean increased by 10.8%. In addition, biosynthesized ZnO also improves plant phenology such as stem height, root volume, and biochemical indicators such as leaf protein and chlorophyll contents. In the rhizosphere, increased chlorophyll content and root volume attract microbial populations that maintain soil biological health. ICP-MS results showed ZnO nanoparticles were distributed in all plant parts, including seeds. However, the concentration of Zn was within the limit of the dietary recommendation. To the best of our knowledge, this is the first holistic study focusing on native P mobilization using ZnO nanoparticles in the life cycle of mung bean plants.

The application of nano materials is one of the current hot spots in agricultural production. The aim of this work was to evaluate the effects of different nano fertilizer synergists on nitrogen (N) utilization and related gene expression in wheat. The experiments were carried out in pot and field conditions at the West-Coast Economic New Area experimental base and Greenhouse of Qingdao Agricultural University. Seven treatments were set up: CK (compound fertilizer), T1 (compound fertilizer + 0.3% nano carbon synergist), T2 (compound fertilizer + 0.3% nano calcium carbonate synergist), T3 (compound fertilizer + 0.3% composite nano synergist), T4 (70% compound fertilizer + 0.3% nano carbon synergist), T5 (70% compound fertilizer + 0.3% nano calcium carbonate synergist), T6 (70% compound fertilizer + 0.3% composite nano synergist). The results showed that compared with CK, the N accumulation of T1, T2, T3, T4, T5 and T6 increased by 40-50%, 30-40%, 55-65%, 20-30%, 15-20% and 30-40%, respectively; and the N use efficiency increased by 12-19%, 9-18%, 16-22%, 5-17%, 4-16% and 10-20% respectively. And the gene expression levels of TaNRT2.2, TaNRT2.3, TaGS1 and TaGS2 in the treatments with synergistic phosphate fertilizer were significantly higher than those in the CK. The application of nano fertilizer synergist can significantly improve N accumulation, N use efficiency, and promote the expression of genes related to N transport and metabolism.© 2023. The Author(s).

With the rising need for sustainable agricultural practices, nano-fertilizers have emerged as an innovative alternative to traditional fertilizers. These advanced fertilizers enhance nutrient use efficiency, promote crop growth, and minimize environmental harm by enabling precise nutrient delivery. This review evaluates various nano-fertilizer application techniques and their influence on plant growth, yield, and quality. Additionally, it explores their interactions with soil composition and microbial communities, emphasizing their role in enzymatic activity and nutrient cycling. While nano-fertilizers offer significant benefits, challenges such as proper dosage regulation, potential toxicity, and long-term ecological effects necessitate further research. This study highlights recent advancements in nano-fertilizer technology and underscores the importance of an integrated approach to optimize agricultural productivity while preserving soil health and environmental sustainability.

Nano fertilizers have emerged as a cutting-edge innovation in agricultural practices, poised to redefine nutrient delivery and management at the plant-soil interface. This review provides a comprehensive overview of the effects and consequences of nano fertilizer application on plant wellness. The inherent properties of nanoparticles allow for enhanced nutrient absorption, precise delivery, and increased bioavailability, potentially revolutionizing traditional fertilization methods. The results, as evidenced by multiple studies, indicate significant improvements in growth parameters, seed production, and overall plant health. Moreover, plants treated with nano fertilizers have shown heightened resistance to both biotic and abiotic stresses. However, while the benefits are promising, concerns arise regarding the ecological persistence of nanoparticles, potential bio-magnification, and implications for human health. A comparative analysis with conventional fertilizers revealed nano fertilizers' superior efficiency, but also brought forth economic considerations and environmental footprints. The current regulatory landscape is dynamic, with policies adapting to the rapid advancements of nanotechnology in agriculture. As research continues to bridge existing gaps, technological advancements are concurrently shaping the future prospects of nano fertilizer application. This review underscores the need for a balanced understanding of the potential and challenges, emphasizing collaborative efforts to harness nano fertilizers' full potential while ensuring ecological and human health safety.

Vegetables accumulate considerable amounts of nitrates that enter the human body through nutrition, causing severe problems. This study aims to determine celery plants’ response to replacing mineral nitrogen fertilizers with bio-nanoparticles. Three different treatments of nano bio-nitrogen fertilizer (20, 30, and 40 ppm) in addition to traditional nitrogen (NH4NO3) treatment (100 kg N/acre) were applied on two celery cultivars (Balady and Utah Tall 52–75). Plant growth parameters, vitamin C, carotenoids, nitrate accumulation, macro-nutrient uptakes, and antioxidant activities were determined at the vegetative marketing stage. Our findings reveal a significant positive impact of replacing conventional nitrogen fertilizers with bio-nano-synthesized forms. Notably, applying bio-nanoparticles improved celery yield efficiency, ranging from 5.1 to 5.8 tons per acre, suggesting a viable alternative to traditional fertilization methods. Furthermore, transitioning from mineral to organic fertilizers in nanoparticle form reduced nitrate accumulation in fresh celery crops, decreasing nitrate levels from 342.5 ppm to as low as 100 ppm. This environmentally conscious approach offers a sustainable solution to mitigate chemical residues and enhance celery’s flavor, nutritional value, and health benefits. Specifically, our results demonstrate alleviated nitrate contents in fresh celery leaves after applying bio-nano-fertilizer. Nitrate levels in treated plants decreased by up to 70.0% compared to traditional fertilization methods. This highlights the potential of organic nano-fertilizers to address concerns related to nitrate accumulation, thereby promoting safer and healthier vegetable consumption. By advocating for organic nano-fertilizers, we propose a promising strategy to optimize celery fertilizing management, ensuring sustainable farming and consumer well-being.